Large multicrystalline silicon ingots, up to 69 cm square cross section
weighing 240 kg have been produced using the Heat Exchanger Method
(HEM). These ingots are produced by adaptation of a single-crystal growth process - HEM -so that controlled directional solidification can
be carried out at low cost. Growth is achieved from the bottom of the
crucible to the top, with a planar solid-liquid interface. Control is
exercised up to the top corners of a square cross-section silicon ingot.
During solidification the ambient is controlled to yield low oxygen and
carbon concentrations. After solidification is complete, the ingot is
in situ annealed to reduce residual stress and produce uniform properties.
From loading to unloading, the cycle time is about 56 hours.
HEM multicrystalline silicon ingots can be used for many high
technology applications. For solar cell applications, HEM silicon is
characterized by long diffusion length, cm-size grains, vertical
orientation of columnar grain boundaries, low oxygen concentrations
and narrow resistivity range. The structural and electrical properties
are uniform from top to bottom and center to edges of the ingot.
In research during investigation for potential of HEM silicon for
photovoltaic applications, the world's highest efficiency multicrystalline
silicon solar cells -18.6% (1 cm2 area) - were fabricated by Georgia
Institute of Technology. HEM silicon is compatible with various solar
cell processing techniques. High efficiency solar cells have been
fabricated worldwide.